Kinetic Study of Ammonium Desorption using Natural Zeolites from Cikalong

Thareqa Abdusattar, Abdul Hadi, Nuryoto Nuryoto, Teguh Kurniawan

Abstract


Household liquid waste which contains ammonium is one of the major contributors to the wastewater effluent. The aim of investigation is to characterize and determine the adsorption capacity of natural zeolites from Cikalong for ammonium removal.  The effect of cations type, K+, Mg2+ and Ca2+, on ammonium desorptions was studied. Kinetic desorption study was also performed and fitted with various kinetic models. According to X-ray diffraction (XRD) pattern, the Cikalong natural zeolites were mordenite and clinoptilolite dominant type.  The morphology of the mordenite phase was appeared as needles shape. The ratio of Si to Al was 6.86 according to X-ray fluorescence (XRF). The surface area was 187 m2/g which was determined by Brunauer–Emmett–Teller (BET) model. Desorption using K+ solution showed the shortest time and the highest rate for ammonium desorption. The calculation using nonlinear method was carried out to optimize the desorption kinetic parameters. The pseudo 1st order desorption kinetics model showed the smallest error with sum of squared error (SSE) 0.00209.


Full Text:

PDF

References


Nejadshafiee, V., & Islami, M. R. 2019. Adsorption capacity of heavy metal ions using sultonemodified magnetic activated carbon as a bio-adsorbent. Materials Science and Engineering: C, 101, 42-52.

Darmayanti, L., Kadja, G. T. M., Notodarmodjo, S., Damanhuri, E., & Mukti, Rino R. 2019. Structural alteration within fly ash-based geopolymers governing the adsorption of Cu2+ from aqueous environment: Effect of alkali activation. Journal of Hazardous Materials, 377, 305- 314.

Kobielska, P. A., Howarth, A. J., Farha, O. K., & Nayak, S. 2018. Metal–organic frameworks for heavy metal removal from water. Coordination Chemistry Reviews, 358, 92-107.

Zhu, W., Wang, J., Wu, D., Li, X., Luo, Y., Han, C., Ma, W., He, S. 2017. Investigating the heavy metal adsorption of mesoporous silica materials prepared by microwave synthesis. Nanoscale Research Letters, 12(1), 323-332.

João, C., Nuno, C., Tiago, M., Luis, S., Ana, F. J., & Mafalda, O. 2019. Stabilisation of high-sulphide tailings with alkali activated fly ash–mechanical performance. MATEC Web of Conferences, 274, 1-6.

Puspitasari, Tita; Ilmi, Moh. Mualliful; Nurdini, Nadya; Mukti, Rino R.; Radiman, Cynthia L.; Darwis, Darmawan; Kadja, Grandprix T. M. (2019). The physicochemical characteristics of natural zeolites governing the adsorption of Pb2+ from aqueous environment. Key Engineering Materials, 811, 92-98.

Hegazi, H. A. 2013. Removal of heavy metals from wastewater using agricultural and industrial wastes as adsorbents. Housing and Building National Research Center, 9, 276-282.

Gandy, J. J., Laurens, I., & Snyman, J. R. 2015. Potentiated clinoptilolite reduces signs and symptoms associated with veisalgia. Clin Exp Gastroenterol, 8, 271-277

Latief, N. A. dan Kusdarto. 2003. Eksplorasi rinci endapan zeolit di Kabupaten Tasikmalaya, Jawa Barat, Direktorat Sumberdaya Mineral, Bandung.ISSN 1411-6723

Coombs, D.S., Alberti, A., Armbruster, T., Artioli, G., Colella, C., Galli, E., Grice, J.D., Liebau, F., Mandarino, J.A., Minato, H., Nickel, E.H., Passaglia, E., Peacor, D.R., Quartieri, S., Rinaldi, R., Ross, M., Sheppard, R.A., Tillmanns, E., and Vezzalini, G. 1997. Recommended nomenclature for zeolite minerals: Report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. Can. Mineral. 35, 1571-1606.

Anita, Diyanah, Saiful Bahri, Nuryoto, Teguh Kurniawan. 2019 Modifikasi Zeolit Alam Bayah Dengan Basa Untuk Aplikasi Eliminasi Amonium Di Dalam Kolam Bandeng. Jurnal Integrasi Proses, ISSN 2302-9048

Hardjatmo, H. 1996. Study the Properties of Some Indonesia Natural Zeolites. One Day Seminar on Mineral Property and Utilization of Natural Zeolite. JSPS-BPPT.




DOI: http://dx.doi.org/10.62870/wcej.v5i1.12103

Refbacks

  • There are currently no refbacks.


Copyright (c) 2021 World Chemical Engineering Journal

WCEJ (e-ISSN: 2443-2261) is published by Chemical Engineering Department, Universitas Sultan Ageng Tirtayasa (UNTIRTA).

This Journal has been indexed by:

  1. Google Scholar
  2. Garuda
  3. Dimensions
  4. Crossref
  5. Open Academic Journal Index
  6. Journal Impact Factor
  7. Cite Factor 
Archives: Resources | Dimensions CrossrefJIFACTOR, Journal Indexing  

 

 

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.