Sensors and Mini Photocatalytic Reactor as a Tool for Measure CO2 Gas from the Degradation of the Detergent Active Compound
Abstract
This study aims to test the performance and feasibility of new tools and methods for analysis of detergent based on the photocatalytic degradation of LAS and ABS, which is a detergent active compound. Testing is done by measuring the CO2 gas formed from the degradation at every one-hour for five hours of reaction. The results of the determination of analytical parameters are as follows, sensitivity: 0.394 to 0.460, the limit of detection: 0.16 mg/L, accuracy: 0.94% to 12.88% and punctilio: 0.12% to 0.14%, the range of linearity: 0.4 mg/L to 2 mg/L. Results of calibration using standard solutions obtained regression equation y = 1.033 x - 77.713 with R2 = 0.988, indicating that the instrument has been calibrated and fit for use for the analysis of LAS and ABS with concentrations above or equal to 25 mg/L. The test results showed that the developed method is practical, effective and efficient.
Full Text:
PDFReferences
Doan H.D., M. Saidi, 2008, Simultaneous removal of metal ions and linear alkylbenzene sulfonate by combined electrochemical and photocatalytic process. J. of Hazard. Mater., doi:10.1016/j.jjhazmat.2008.01.102.
Reiser R., Toljander.H.O., and Giger. M., 1997. Determination of alkylbenzenesulfonates in resent sedimen by gas cromatography mass spectrometry. J. Anal. Chem. 69(23) :4923-4930.
Ottó Horváth and Róbert Huszánk, 2003, Degradation of surfactans by hydrokxyl radicals photogenerated hydroxoiron(III) complexes, Photochem Photobiol. Sci., 2, 960-966.
Hidaka H., Takayoshi K., Teruo K., and Nick S., 2004, Dynamics and mechanistic features in the photocatalyzed oxidation of disulfonated anionic surfactants on the surface of UV-irradiated titania nanoparticles, New J. Chem., 28, 1100 – 1106.
Jarnuzi Gunlazuardi, Faizal Hari Fajar, Heny Suseno, (2002), Penentuan Karbon Organik Total Melalui Oksidasi Secara Fotokatalitik-Konduktometri, Prosiding Seminar Nasional Himpunan Kimia Indonesia , 28-29 Mei, Di UPI, Bandung.
Herman J.M., 1999, Heterogenous Photocatalysis: Fundamental and Applications to the Removal of Various Tipes of Aqueous Pollutans, Catal.Today, 53, 115-129.
Dong H. K., Ji Y.Y., Hee C. P., Kwang H. K., 1999, CO2-sensing characteristics of SnO2 thick film by coating lannthanum oxide, Sensors and Actuators, B 62, 61-66.
EPA, 1983, Methylene Blue Active Substances (MBAS), Method 425.1(colorimetri), ,Monitoring And Support Laboratory, Office of Research and Development, U.S. Enviromental Protection Agency.
Jurado E., Fernandez M., Serrano J., Nunez-Olea, Luzon G, Lechuga M., 2006, Simplified spectrophotometric method using methylene blue for determining anionic surfactants : Applications to the study of primary biodegradation in earobic screening tests, Chemosphere , 65, 278-285.
Hu Y., Noriko W., Koichiro T., Masakazu A. ( 2006), Photo-assisted synthesis of V and Ti-containing MCM-41 under UV light irradiation and thear reactivity for the photooxidation of propane, Catalysis Today , 120, 139-144.
Akyuz & Roberts, 2002; Determination of Linear Alkylbenzene Sulphonates and their Biodegradation Intermediates by Isocratic RP-HPLC, Turk J Chem, 26 , 669 ; 679.
Leon V.M., C. Lo´pez, P.A. Lara-Martı´n, D. Prats, P. Varo, E. Gonza´lez-Mazo, 2006, Removal of linear alkylbenzene sulfonates and their degradation intermediates at low temperatures during activated sludge treatment, J. Chemosphere, 64, 1157-1166.
Caulcutt dan Boddy, 1983, Statistics for analytical chemists London ; New York : Chapman and Hall, 1983.
Massart et al., (1980),Evaluation and Optimization of Laboratory Methods and Analytical Prosedures, Elsevier/North-Holland Inc. New York, N.Y. 10017.
Miller and Miller,2000, Statistics and Chemometrics for Analytical Chemistry, 4th ed., Pearson Education Limited, Edinburgh Gate, Harlow, Essex CM 20 2JE, England.
Skoog et al.,1996). Analytical Chemistry, seventh Editions, Saunders College Publishing, London, Sydney, Tokyo.
Jarnuzi Gunlazuardi, Faizal Hari Fajar, Heny Suseno, (2002), Penentuan Karbon Organik Total Melalui Oksidasi Secara Fotokatalitik-Konduktometri, Prosiding Seminar Nasional Himpunan Kimia Indonesia , 28-29 Mei, Di UPI, Bandung.
Reiser R., Toljander.H.O., and Giger. M., 1997. Determination of alkylbenzenesulfonates in resent sedimen by gas cromatography mass spectrometry. J. Anal. Chem. 69(23) :4923-4930.
Fernandez J., et al., 2004, Determination of photodegradation and ozonation by products of limear alkylbenzene sulfonates by liquid chomatography and ion chromatography under controlled labpratory experiments, J. Talanta, 64, 69-79.
Kristian K. B Pete., Martin H., Peter R., K. Hendriksen., and Jan Sorensen, 2001, Taxic Effects of Linear Alkylbenzene Sulfonate on Matabolic Activity, Growth Rate, and Microcolony Formation of Nitrosomonas and Nitrosospira Strains, Applied and Environmental Microbiology, 67(6), 2489-2498.
Aboulhassan M.A., Souabi S., Yacoubi A., amd Baudu M., 2006, Removal of surfactant from industrial wastewaters by coagulation flocculation process, International Journal of Environment Science and Technology, 3(4), 327-332.
Abu Hassan M.A., Ian S Metcalfe, 2003, Catalytic Wet Air Oxidation Of Linear Alkylbenzene Sulphonate, Journal of Chemical and Natural Resources Engineering, 1,1-14.
Amat A. M., Arques A., Miranda M. A., Vincente R., and Segui S., (2006), Degradation of two Commercial Anionic Surfactants by Means of Ovone and/or UV Irradiation, Environmental Engineering Science, 24(6), 790-796.
Arifin, 2007, Tinjauan dan Evaluasi Proses Kimia (Koagulasi, Netralisasi, Desinfeksi) di Instalasi Pengolahan Air Minum Cikokol, Tanggerang : PT. Tirta Kencana Cahaya Mandiri.
Cosma C., Nitoi I., Patroescu, 2003, Pre-Treatment technology of Waste Water Discharged from The Washing Process of ‘Denim’ Textile Texture, Journal of Environmental Protection and Ecology, 4(3), 712-716.
Daneshvar, Nazameddin; Salari, Daryoosh and Behnasuady, Mohammad Aly, 2002, Decomposition of Anionic Sodium Dodecylbenzene Sulfonate by UV/TiO2 and UV/H2O2 Processes a- Comparison of Reaction Rates, Iran J.Chem. & Chem. Eng., 21, 55-62.
Horváth O. and Huszánk R., 2003, Degradation of surfactans by hydrokxyl radicals photogenerated from hydroxoiron(III) complexes, Photochem Photobiol. Sci., 2, 960-966.
Merhab M., Tabrizi B.G., Nabil A. J., 2005, Effects of pilot-plant photochemical pre-treatment (UV/H2O2) on the biodegradability of aqueous linear alkylbenzene sulfonat (LAS), International Journal of Photoenergy, 7, 169-174.
SNI (Standar Nasional Indonesia) 06-6989.51 , 2005, Cara uji kadar surfaktan anionik dengan spektrofotometer secara biru metilen, Badan Standardisasi Nasional, ICS 13.060.01.
SNI (Standar Nasional Indonesia) 6989.59 , 2008, Metoda pengambilan contoh air limbah, Badan Standardisasi Nasional, ICS 13.060.50.
DOI: http://dx.doi.org/10.62870/wcej.v5i2.12289
Refbacks
- There are currently no refbacks.
Copyright (c) 2021 World Chemical Engineering Journal
WCEJ (e-ISSN: 2443-2261) is published by Chemical Engineering Department, Universitas Sultan Ageng Tirtayasa (UNTIRTA).
This Journal has been indexed by:
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.