Utilization of Agricultural and Organic Waste as Eco-Friendly Biomass-based Adsorbents

Hendrini Pujiastuti, Sarah Rafidah Aziz

Abstract


The development of effective and sustainable remediation techniques is required due to the growing environmental contamination brought on by industrial activities, especially from heavy metals and organic pollutants. The purpose of this review is to evaluate critically the potential of biomass-based adsorbents made from organic and agricultural waste for use in environmental remediation, specifically in the treatment of soil and water. The study assesses the surface properties, functional groups, and adsorption mechanisms of several bio-adsorbents and groups them according to their sources, including activated carbon, agricultural residues, and biochar. The impact of chemical and physical changes on improving adsorption performance is also thoroughly examined. The results show that these environmentally friendly materials have notable adsorption capacities and provide a sustainable, scalable, and affordable substitute for traditional synthetic adsorbents. The study adds to the expanding corpus of research that supports the circular economy's waste valuation principles and emphasises the usefulness of green environmental management techniques.


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Abiodun, O. A. O., Oluwaseun, O., Oladayo, O. K., Abayomi, O., George, A. A., Opatola, E., … Omotayo, I. A. (2023). Remediation of Heavy Metals Using Biomass-Based Adsorbents: Adsorption Kinetics and Isotherm Models. Clean Technologies, 5(3), 934–960. https://doi.org/10.3390/cleantechnol5030047

Ahmad, T., Rafatullah, M., Ghazali, A., Sulaiman, O., & Hashim, R. (2011). Oil palm biomass-based adsorbents for the removal of water pollutantsa review. Journal of Environmental Science and Health - Part C Environmental Carcinogenesis and Ecotoxicology Reviews, 29(3), 177–222. https://doi.org/10.1080/10590501.2011.601847

Amusat, S. O., Kebede, T. G., Dube, S., & Nindi, M. M. (2021). Ball-milling synthesis of biochar and biochar–based nanocomposites and prospects for removal of emerging contaminants: A review. Journal of Water Process Engineering, 41(February), 101993. https://doi.org/10.1016/j.jwpe.2021.101993

Bhatnagar, A., Sillanpää, M., & Witek-Krowiak, A. (2015). Agricultural waste peels as versatile biomass for water purification - A review. Chemical Engineering Journal, 270, 244–271. https://doi.org/10.1016/j.cej.2015.01.135

Bolisetty, S., Peydayesh, M., & Mezzenga, R. (2019). Sustainable technologies for water purification from heavy metals: review and analysis. Chemical Society Reviews, 48(2), 463–487. https://doi.org/10.1039/c8cs00493e

Cite, P., & Published, T. H. E. (2019). Low-cost biomass as adsorbents for the removal of heavy metal ions from industrial wastewater used for crop irrigation in developing countries SUSTAIN WATER , SANITATION AND HYGIENE SERVICES Low-cost biomass as adsorbents for the removal of heavy metal fr, 0–7.

Da̧browski, A. (2001). Adsorption - From theory to practice. Advances in Colloid and Interface Science, 93(1–3), 135–224. https://doi.org/10.1016/S0001-8686(00)00082-8

Fang, Y., Yang, K., Zhang, Y., Peng, C., Robledo-Cabrera, A., & López-Valdivieso, A. (2021). Highly surface activated carbon to remove Cr(VI) from aqueous solution with adsorbent recycling. Environmental Research, 197(March). https://doi.org/10.1016/j.envres.2021.111151

Fiyadh, S. S., AlSaadi, M. A., Jaafar, W. Z., AlOmar, M. K., Fayaed, S. S., Mohd, N. S., … El-Shafie, A. (2019). Review on heavy metal adsorption processes by carbon nanotubes. Journal of Cleaner Production, 230, 783–793. https://doi.org/10.1016/j.jclepro.2019.05.154

Foo, K. Y., & Hameed, B. H. (2010). Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal, 156(1), 2–10. https://doi.org/10.1016/j.cej.2009.09.013

Ge, M., Xi, Z., Zhu, C., Liang, G., Yang, Y., Hu, G., … Alam, S. M. J. (2019). Adsorption process and properties analyses of a pure magadiite and a modified magadiite on rhodamine-B from an aqueous solution. Processes, 7(9), 1–12. https://doi.org/10.3390/pr7090565

Haghseresht, F., & Lu, G. Q. (1998). Adsorption characteristics of phenolic compounds onto coal-reject-derived adsorbents. Energy and Fuels, 12(6), 1100–1107. https://doi.org/10.1021/ef9801165

Harshala, K., & Wagh, N. D. (2022). Use of Agricultural Waste-Based Biosorbents for the Removal of Heavy Metals from Aqueous Solution: A Review. Nature Environment and Pollution Technology, 21(3), 1003–1014. https://doi.org/10.46488/NEPT.2022.v21i03.007

Hoang, A. T., Kumar, S., Lichtfouse, E., Cheng, C. K., Varma, R. S., Senthilkumar, N., … Nguyen, X. P. (2022). Remediation of heavy metal polluted waters using activated carbon from lignocellulosic biomass: An update of recent trends. Chemosphere, 302, 1–80. https://doi.org/10.1016/j.chemosphere.2022.134825

Jain, A., Balasubramanian, R., & Srinivasan, M. P. (2016). Hydrothermal conversion of biomass waste to activated carbon with high porosity: A review. Chemical Engineering Journal, 283, 789–805. https://doi.org/10.1016/j.cej.2015.08.014

Li, R., Zhang, T., Zhong, H., Song, W., Zhou, Y., & Yin, X. (2021). Bioadsorbents from algae residues for heavy metal ions adsorption: chemical modification, adsorption behaviour and mechanism. Environmental Technology (United Kingdom), 42(20), 3132–3143. https://doi.org/10.1080/09593330.2020.1723711

Mahfoudhi, N., & Boufi, S. (2017). Nanocellulose as a novel nanostructured adsorbent for environmental remediation: a review. Cellulose, 24(3), 1171–1197. https://doi.org/10.1007/s10570-017-1194-0

Manzoor, F., Karbassi, A., & Golzary, A. (2019). Removal of Heavy Metal Contaminants from Wastewater by Using Chlorella vulgaris Beijerinck: A Review . Current Environmental Management, 6(3), 174–187. https://doi.org/10.2174/2212717806666190716160536

Murtaza, G., Ahmed, Z., Usman, M., Areeb, A., Ditta, A., Ullah, Z., & Mahmood, F. (2021). Impacts on biochar aging mechanism by eco-environmental factors. Proceedings of the International Academy of Ecology and Environmental Sciences, 2020(3), 97–104. Retrieved from www.iaees.org

Prasath, R. R., Muthirulan, P., & Kannan, N. (2014). Agricultural wastes as a low cost adsorbents for the removal of Acid Blue 92 dye: A Comparative study with Commercial activated carbon. IOSR Journal of Agriculture and Veterinary Science, 7(2), 19–32. https://doi.org/10.9790/2380-07231932

Rizal, S., Olaiya, F. G., Saharudin, N. I., Abdullah, C. K., Olaiya, N. G., Mohamad Haafiz, M. K., … Abdul Khalil, H. P. S. (2021). Isolation of textile waste cellulose nanofibrillated fibre reinforced in polylactic acid-chitin biodegradable composite for green packaging application. Polymers, 13(3), 1–15. https://doi.org/10.3390/polym13030325

Sen, T. K. (2023). Agricultural Solid Wastes Based Adsorbent Materials in the Remediation of Heavy Metal Ions from Water and Wastewater by Adsorption: A Review. Molecules, 28(14). https://doi.org/10.3390/molecules28145575

Shakoor, M. B., Ye, Z. L., & Chen, S. (2021). Engineered biochars for recovering phosphate and ammonium from wastewater: A review. Science of the Total Environment, 779, 146240. https://doi.org/10.1016/j.scitotenv.2021.146240

Sud, D., Mahajan, G., & Kaur, M. P. (2008). Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions - A review. Bioresource Technology, 99(14), 6017–6027. https://doi.org/10.1016/j.biortech.2007.11.064

Taiwo, A. F., & Chinyere, N. J. (2016). Sorption Characteristics for Multiple Adsorption of Heavy Metal Ions Using Activated Carbon from Nigerian Bamboo. Journal of Materials Science and Chemical Engineering, 04(04), 39–48. https://doi.org/10.4236/msce.2016.44005

Taylor, M. P., Isley, C. F., & Glover, J. (2019). Prevalence of childhood lead poisoning and respiratory disease associated with lead smelter emissions. Environment International, 127(April), 340–352. https://doi.org/10.1016/j.envint.2019.01.062

Urrutia, C., Yañez-Mansilla, E., & Jeison, D. (2019). Bioremoval of heavy metals from metal mine tailings water using microalgae biomass. Algal Research, 43(August), 101659. https://doi.org/10.1016/j.algal.2019.101659

Vaithyanathan, V. K., Goyette, B., & Rajagopal, R. (2023). A critical review of the transformation of biomass into commodity chemicals: Prominence of pretreatments. Environmental Challenges, 11(January), 100700. https://doi.org/10.1016/j.envc.2023.100700

Wong, Y. C., Szeto, Y. S., Cheung, W. H., & McKay, G. (2004). Adsorption of acid dyes on chitosan - Equilibrium isotherm analyses. Process Biochemistry, 39(6), 695–704. https://doi.org/10.1016/S0032-9592(03)00152-3

Yousef, R., Qiblawey, H., & El-Naas, M. H. (2020). Adsorption as a process for produced water treatment: A review. Processes, 8(12), 1–22. https://doi.org/10.3390/pr8121657

Zhang, H., Chen, C., Gray, E. M., & Boyd, S. E. (2017). Effect of feedstock and pyrolysis temperature on properties of biochar governing end use efficacy. Biomass and Bioenergy, 105, 136–146. https://doi.org/10.1016/j.biombioe.2017.06.024




DOI: http://dx.doi.org/10.62870/wcej.v9i1.33760

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