SINTESIS, KARAKTERISASI DAN APLIKASI TIMAH TETRAKLORIDA PENTAHIDRAT

Marta Pramudita, Alia Badra Pitaloka, Rahmayetti Rahmayetti, Jayanudin Jayanudin, Saepurahman Saepurahman, Teguh Kurniawan, Selfira Arum Andadari

Abstract


Indonesia is one of the world's largest tin-producing countries, but its downstream industry is not well developed. One of the chemical products derived from tin is SnCl4.5H2O. Several commercial production routes are reviewed in this paper. In addition, SnCl4.5H2O characterization techniques from advanced analytical instruments to titration analysis are also discussed. Commercial applications of SnCl4.5H2O products include catalysts, polyvinyl chloride (PVC) stabilizers, and dyes. The latest developments regarding the potential of SnCl4.5H2O as a catalyst are also reviewed in this paper.


Keywords


Tin, synthesis; characterization; tin tetrachloride pentahydrate; application

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References


Acros Organics (2008) Tin(IV) chloride pentahydrate,98+%,extra pure.

Barnes, J. C., Sampson, H. A. and Weakley, T. J. R. (1980) ‘Crystal structures of di-µ-hydroxo-bis[aquatrichlorotin ( IV )]–1,4-dioxan (1/3), di-µ-hydroxo-bis[aquatrichlorotin( IV )]–1,8-epoxy-p-menthane (1/4), di-µ-hydroxo-bis[aquatribromotin ( IV )]–1,8-epoxy-p-menthane (1/4), di’, J. Chem. Soc., Dalton Trans., (6), pp. 949–953. doi: 10.1039/DT9800000949.

Biedenkapp, D. and Weiss, A. (1968) ‘Kernquadrupolresonanz(KQR)-Spektroskopie an 35Cl in Komplexverbindungen* von Arsentrichlorid, AsCl3, mit einigen aromatischen Kohlenwasserstoffen’, Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences. doi: 10.1515/znb-1968-0210.

Brinzari, V. et al. (2002) ‘Morphological rank of nano-scale tin dioxide films deposited by spray pyrolysis from SnCl4·5H2O water solution’, Thin Solid Films, 408(1–2), pp. 51–58. doi: 10.1016/S0040-6090(02)00086-X.

Burke, J. J. and Lauterbur, P. C. (1961) ‘Sn119 Nuclear Magnetic Resonance Spectra’, Journal of the American Chemical Society. doi: 10.1021/ja01463a016.

CEEA Erasmus (no date) TITRATION OF CHLORIDE IONS WITH SILVER NITRATE.

Central Drug House (no date) STANNIC CHLORIDE PENTAHYDRATE.

Chaki, S. H. et al. (2013) ‘Wet chemical synthesis and characterization of SnS2 nanoparticles’, Applied Nanoscience (Switzerland), 3(3), pp. 189–195. doi: 10.1007/s13204-012-0123-7.

Chemicals, T. S. (no date) Tin(IV) chloride pentahydrate, 98+%, extra pure.

Chen, D. et al. (2015) ‘SnCl4·5H2O: A highly efficient catalyst for hydration of alkyne’, Applied Sciences (Switzerland), 5(2), pp. 114–121. doi: 10.3390/app5020114.

Genge, A. R. J. et al. (2004) ‘Hydrates of tin tetrachloride’, Acta Crystallographica Section C: Crystal Structure Communications, 60(4). doi: 10.1107/S0108270104005633.

Han, S. et al. (2005) ‘Simple synthesis of hollow tin dioxide microspheres and their application to lithium-ion battery anodes’, Advanced Functional Materials, 15(11), pp. 1845–1850. doi: 10.1002/adfm.200500243.

Hennings, E., Schmidt, H. and Voigt, W. (2014) ‘Crystal structure of tin(IV) chloride octahydrate’, Acta Crystallographica Section E Structure Reports Online, 70(12), pp. 480–482. doi: 10.1107/S1600536814024271.

Himedia (no date) Tin (IV) chloride pentahydrate (Stannic chloride pentahydrate).

Ho, Y. S., Chen, T. S. and Yang, W. D. (2010) ‘The effect of tin precursors on the formation of Zr0.8Sn 0.2TiO4 nano-powder by sol gel process’, Journal of Sol-Gel Science and Technology, 53(3), pp. 613–618. doi: 10.1007/s10971-009-2139-3.

Honeywell-Fluka (2018) Tin(IV) chloride pentahydrate.

Https://www.ekon.go.id/publikasi/detail/5196/wujudkan-visi-indonesia-emas-2045-pemerintah-luncurkan-rencana-pembangunan-jangka-panjang-nasional-rpjpn-2025-2045 (no date) Wujudkan Visi “Indonesia Emas 2045”, Pemerintah Luncurkan Rencana Pembangunan Jangka Panjang Nasional (RPJPN) 2025-2045.

Hu, P. et al. (2017) ‘Hydrothermal synthesis and photocatalytic properties of WO3 nanorods by using capping agent SnCl4·5H2O’, Physica E: Low-Dimensional Systems and Nanostructures, 92, pp. 12–16. doi: 10.1016/j.physe.2017.05.004.

Ichiba, S. et al. (1968) ‘ Mössbauer Effect of the 119 Sn in the Molecular Complexes of Tin Tetrachloride with Some Aliphatic Compounds ’, Bulletin of the Chemical Society of Japan. doi: 10.1246/bcsj.41.49.

Kirk, R. E., Othmer, D. F. and Newburger, S. H. (1953) ‘Encyclopedia of Chemical Technology’, Journal of AOAC INTERNATIONAL, 36(4), pp. 1190a – 1191. doi: 10.1093/jaoac/36.4.1190a.

Mellor, J. W. (1927) ‘A Comprehensive Treatise on Inorganic and Theoretical Chemistry Vol. VII - Ti, Zr, Hf, Th, Ge, Sn, Pb, Inert Gases’, VII, pp. 1–958.

Morrison, B. J. and Musgrave, O. C. (2002) ‘Condensations of benzil with phenols and aryl ethers mediated by tin(IV) chloride pentahydrate’, Tetrahedron, 58(21), pp. 4255–4260. doi: 10.1016/S0040-4020(02)00357-5.

Negita, H., Okuda, T. and Mishima, M. (1969) ‘The Bond Character of the Sn–Cl Bonds in the Hydrates of Tin (IV) Chloride’, Bulletin of the Chemical Society of Japan, 42(9). doi: 10.1246/bcsj.42.2509.

Pearce, J. and Wallace, T. (2015) Tin Chemicals Roadmap 2015.

Santos, T. G., Silva, A. O. S. and Meneghetti, S. M. P. (2019) ‘Comparison of the hydrothermal syntheses of Sn-magadiite using Na2SnO3 and SnCl4·5H2O as the precursors’, Applied Clay Science, 183(August), p. 105293. doi: 10.1016/j.clay.2019.105293.

Semenov, S. N. et al. (2005) ‘Crystal structures of tin(IV) chloride hydrates’, Mendeleev Communications, 15(5), pp. 205–207. doi: 10.1070/MC2005v015n05ABEH002130.

Sigma-Aldrich (no date) Tin(IV) chloride pentahydrate.

Solís-Casados, D. et al. (2009) ‘Characterization and Photocatalytic Performance of Tin Oxide’, Industrial & Engineering Chemistry Research, 48(3), pp. 1249–1252. doi: 10.1021/ie800604u.

Svyatkina, L. I. et al. (1984) ‘Polymerization of 10-vinyl phenothiazine in presence of thin chlorides’, Polymer Science U.S.S.R., 26(6), pp. 1314–1320. doi: 10.1016/0032-3950(84)90041-8.

Taylor, M. J., Milligan, J. R. and Parnell, D. L. (1972) ‘Vibrational spectra of concentrated aqueous solutions and solvent extracts of the tin(IV) and antimony(V) chloride systems’, Journal of Inorganic and Nuclear Chemistry. doi: 10.1016/0022-1902(72)80145-3.

Teli, M. D. (2015) Advances in the dyeing and printing of silk, Advances in Silk Science and Technology. Elsevier Ltd. doi: 10.1016/B978-1-78242-311-9.00004-5.

Wang, J. et al. (2020) ‘One-pot synthesis and gas sensitivity of SnO2 nanoparticles prepared using two Sn salts of SnCl4·5H2O and SnCl2·2H2O’, Applied Physics A: Materials Science and Processing, 126(1), pp. 1–7. doi: 10.1007/s00339-019-3230-4.

Wang, M., Song, Z. and Liang, Y. (2010) ‘SnCl4·5H2O-CATALYZED SYNTHESIS OF β-AMINO CARBONYL COMPOUNDS VIA A DIRECT MANNICH-TYPE REACTION’, Preparative Biochemistry & Biotechnology, 41(1), pp. 1–6. doi: 10.1080/10826068.2010.489008.

Wang, Y. et al. (2017) ‘Electrodeposition of tin coatings having enhanced corrosion resistance and anti-discoloration performance from tin (IV) sols’, Surface and Coatings Technology, 331(Iv), pp. 90–96. doi: 10.1016/j.surfcoat.2017.10.033.

Xi-an, M., Xiao-zeng, Y. and An-bang, D. (1989) ‘119Sn NMR spectra of SnCl4·5H2O in H2O/HCl solutions’, Inorganica Chimica Acta. doi: 10.1016/S0020-1693(00)83496-9.

Yunnan, T. C. C. (no date) ‘2. Paten CN102849789A – Preparation method for stannic chloride pentahydrate, 2012’




DOI: http://dx.doi.org/10.36055/jip.v12i2.22830

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