MICROWAVE-ASSISTED HYDRODISTILLATION EXTRACTION OF CRUDE OIL FROM ARUMANIS MANGO KERNEL (Mangifera indica L.)

Lutfia Rahmiyati, Desi Riana Saputri, Misbahudin Alhanif, Naufal Brain Shifa, Daffa Ahsanul Akbar, Wika Atro Auriyani, Damayanti Damayanti, Yunita Fahni, Andri Sanjaya, Edwin Rizki Safitra, Muhammad Triyogo Adiwibowo, Rihardian Maulana Wicaksono

Abstract


Arumanis mango seeds (Mangifera indica L.) are generally underutilized and still considered agricultural waste. Mango seeds offer various benefits, including antioxidant properties, cholesterol-lowering effects, and natural antibiotic activity. This study aims to determine the yield of mango kernel extract, evaluate the influence of solvent type and extraction time on extraction efficiency, and identify the chemical composition of the extract. The extraction process was carried out using the microwave-assisted hydrodistillation (MAHD) at 375 watts, employing three types of solvents: ethanol, ethyl acetate, and n-hexane, with extraction times of 30, 60, and 90 minutes. The chemical composition of the extracts was analyzed using gas chromatography-mass spectrometry (GC-MS) analysis. The results showed that the highest yield was obtained using ethanol at an extraction time of 30 minutes, yielding 40.342%. Based on GC-MS analysis, in the n-hexane at a 90-minute extraction time, the most abundant fatty acid detected was butyric acid, with a retention time of 14.06 minutes and a peak area of 9.852%. Meanwhile, the most dominant compound was hydroxymethyl furfuraldehyde (HMF), which appeared at a retention time of 22.09 minutes with a peak area of 12.437%.


Keywords


Extraction time; Fatty acid; Mango seed; Microwave-assisted hydrodistillation; Solvent

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Al-Marzoqi, A. H., Hameed, I. H., & Idan, S. A. (2015). Analysis of bioactive chemical components of two medicinal plants (Coriandrum sativum and Melia azedarach) leaves using gas chromatography-mass spectrometry (GC-MS). African Journal of Biotechnology, 14(40), 2812-2830. https://doi.org/10.5897/ajb2015.14956

Antony, A., & Farid, M. (2022). Effect of temperatures on polyphenols during extraction. Applied Sciences, 12(4), 2107. https://doi.org/10.3390/app12042107

Anwar, J., Shafique, U., Rehman, R., Salman, M., Dar, A., Anzano, J. M., ... & Ashraf, S. (2015). Microwave chemistry: Effect of ions on dielectric heating in microwave ovens. Arabian Journal of Chemistry, 8(1), 100-104. https://doi.org/10.1016/j.arabjc.2011.01.014

Badan Pusat Statistik. (2024). Produksi tanaman buah–buahan dan sayuran tahunan menurut jenis tanaman, 2023. https://www.bps.go.id/id/statistics-table/3/WXpSVU5uUTBOSEl5WVhGQmVESTVSVnBSVlhWeVVUMDkjMyMwMDAw/produksi-tanaman-buah-buahan-dan-sayuran-tahunan-menurut-jenis-tanaman.html?year=2024

Balacuit, J. N. G., Guillermo, J. D. A., Buenafe, R. J. Q., & Soriano, A. N. (2021). Comparison of microwave-assisted extraction to soxhlet extraction of mango seed kernel oil using ethanol and n-hexane as solvents. ASEAN Journal of Chemical Engineering, 21(2), 158–169. https://doi.org/10.22146/ajche.63533

Bitwell, C., Indra, S. Sen, Luke, C., & Kakoma, M. K. (2023). A review of modern and conventional extraction techniques and their applications for extracting phytochemicals from plants. Scientific African, 19, e01585. https://doi.org/10.1016/j.sciaf.2023.e01585

Choudhary, A., Kumar, V., Kumar, S., Majid, I., Aggarwal, P., & Suri, S. (2020). 5-Hydroxymethylfurfural (HMF) formation, occurrence and potential health concerns: Recent developments. Toxin Reviews, 40(4), 545–561. https://doi.org/10.1080/15569543.2020.1756857

Chy, M. W. R., Ahmed, T., Iftekhar, J., Islam, M. Z., & Rana, M. R. (2024). Optimization of microwave-assisted polyphenol extraction and antioxidant activity from papaya peel using response surface methodology and artificial neural network. Applied Food Research, 4(2), 100591. https://doi.org/10.1016/j.afres.2024.100591

Deshmukh, G., & Manyar, H. (2020). Production pathways of acetic acid and its versatile applications in the food industry. In Biomass. IntechOpen. https://doi.org/10.5772/intechopen.92289

Fan, W., Verrier, C., Queneau, Y., & Popowycz, F. (2019). 5-hydroxymethylfurfural (HMF) in organic synthesis: A review of its recent applications towards fine chemicals. Current Organic Synthesis, 16(4), 583–614. https://doi.org/10.2174/1570179416666190412164738

Ghaffar, N., & Perveen, A. (2024). Solvent polarity effects on extraction yield, phenolic content, and antioxidant properties of Malvaceae family seeds: a comparative study. New Zealand Journal of Botany. https://doi.org/10.1080/0028825X.2024.2392705

Gurjar, H. R., & Raj, J. D. (2022). Extraction of mango kernel (Magnifera indica) oil. Asian Journal of Dairy and Food Research, 41(3), 361–364. https://doi.org/10.18805/ajdfr.DR-1855

Karunanithi, B., Bogeshwaran, K., Tripuraneni, M., & Reddy, S. K. (2015). Extraction of mango seed oil from mango kernel. International Journal of Engineering Research and Development, 11(11), 32-41.

Koesprimadisari, A. R., Arrisujaya, D., & Syafdaningsih, R. (2018). Uji kandungan hidroksimetilfurfural (HMF) sebagai parameter kualitas madu. Jurnal Sains Natural, 6(2), 44. https://doi.org/10.31938/jsn.v6i2.159

Loi, C. C., Eyres, G. T., Silcock, P., & John Birch, E. (2020). Application of a novel instantized glycerol monooleate ingredient in a protein-stabilized oil-in-water emulsion. Foods, 9(9). https://doi.org/10.3390/foods9091237

López-Salazar, H., Camacho-Díaz, B. H., Ocampo, M. A., & Jiménez-Aparicio, A. R. (2023). Microwave-assisted extraction of functional compounds from plants: A review. Bioresources, 18(3), 6614. https://doi.org/10.15376/BIORES.18.3.Lopez‑Salazar

Manna, D., Lo, R., Nachtigallová, D., Trávníček, Z., & Hobza, P. (2023). The impact of the solvent dielectric constant on a NH3 dative bond depends on the nature of the lewis electron‐pair systems. Chemistry–A European Journal, 29(35), e202300635. https://doi.org/10.1002/chem.202300635

Mariod, A. A., Saeed Mirghani, M. E., & Hussein, I. (2017). Mangifera indica mango seed kernel oil. Unconventional Oilseeds and Oil Sources, 227–232. https://doi.org/10.1016/b978-0-12-809435-8.00034-2

Mas’ud, F., Indriati, S., Todingbua, A., Rifai, A., & Sayuti, M. (2021). Mango seed kernel oil extraction with ethanol: Optimization of oil yield and polyphenol. Chemical Industry and Chemical Engineering Quarterly, 27(3), 207-214. https://doi.org/10.2298/CICEQ200128039M

Mas’ud, F., & Puspitasari, P. (2017). Studi pendahuluan ekstraksi bertingkat minyak biji mangga arumanis (Mangifera indica) menggunalan pelarut n-heksan dan etanol. INTEK: Jurnal Penelitian, 4(1), 42-48. https://doi.org/10.31963/intek.v4i1.92

Mohamad, M. H., Awang, R., & Yunus, W. M. Z. W. (2011). A review of acetol: Application and production. American Journal of Applied Sciences, 8(11), 1135–1139. https://doi.org/10.3844/ajassp.2011.1135.1139

Pratiwi, L., Fudholi, A., Martien, R., & Pramono, S. (2016). Ethanol extract, ethyl acetate extract, ethyl acetate fraction, and n-heksan fraction mangosteen peels (Garcinia mangostana l.) as source of bioactive substance free-radical scavengers. JPSCR: Journal of Pharmaceutical Science and Clinical Research, 1(2), 71. https://doi.org/10.20961/jpscr.v1i2.1936

Queffelec, J., Beraud, W., Dolores Torres, M., & Domínguez, H. (2024). Advances in obtaining ready to use extracts with natural solvents. Sustainable Chemistry and Pharmacy, 38(December 2023), 101478. https://doi.org/10.1016/j.scp.2024.101478

Rudiana, T., Nurbayti, S., Ashari, T. H., Zhorif, S. A., & Suryani, N. (2023). Comparison of maceration and soxhletation methods on the antioxidant activity of the Bouea macrophylla griff plant. Jurnal Kimia Valensi, 9(2), 244–252. https://doi.org/10.15408/jkv.v9i2.35239

Saleem, K., Perveen, S., Sarwar, N., Latif, F., Pervaiz Akhtar, K., & Imran Arshad, H. M. (2013). Identification of phenolics in mango leaves extract and their allelopathic effect on canary grass and wheat. Pakistan Journal of Botany, 45(5), 1527–1535.

Saputri, D. R., Listyadevi, Y. L., Adiwibowo, M. T., Alhanif, M., Damayanti, D., Fahni, Y., Auriyani, W. A., Sanjaya, A., Sufra, R., Yuniarti, R., Yusupandi, F., Syahriantoro, N. A., & Kurniawansyah, A. (2023). The effect of solvent type on the extraction of soybean crude oil and its laboratory-scale cost analysis. Teknika: Jurnal Sains Dan Teknologi, 19(2), 129. https://doi.org/10.36055/tjst.v19i2.22059

Sarah, M., & Juwairiah, S. (2021). Turpentine oil extraction from pine resin by microwave assisted hydro-distillation (MAHD) technique. IOP Conference Series: Materials Science and Engineering, 1122(1), 012105. https://doi.org/10.1088/1757-899x/1122/1/012105

Shapla, U. M., Solayman, M., Alam, N., Khalil, M. I., & Gan, S. H. (2018). 5-Hydroxymethylfurfural (HMF) levels in honey and other food products: effects on bees and human health. Chemistry Central Journal, 12(1), 1–18. https://doi.org/10.1186/s13065-018-0408-3

Sipra, B. S., Dhal, K., & Padhi, S. (2023). A comparative analysis of phytochemical and biochemical activities of two varieties of mango seed kernels. substance, 4, 5. https://doi.org/10.30574/ijsra.2023.10.2.0814

Siregar, G. B. V., Simanjuntak, E. A. I. A. B., Saputri, D. R., Fahni, Y., Mustafa, M., Sufra, R., ... & Alhanif, M. (2024). Microwave-assisted extraction of tannin from papaya leaves (Carica papaya linn): The effect of solvent ratio and microwave power. Jurnal Integrasi Proses, 13(1), 34-42.

Wu, S., Tokuda, M., Kashiwagi, A., Henmi, A., Okada, Y., Tachibana, S., & Nomura, M. (2015). Evaluation of the fatty acid composition of the seeds of Mangifera indica L. and their application. Journal of Oleo Science, 64(5), 479–484. https://doi.org/10.5650/jos.ess14238

Yadav, D., Pal, A. K., Singh, S. P., & Sati, K. (2022). Phytochemicals in mango (Mangifera indica) parts and their bioactivities: A Review. Crop Research, 57(1&2), 79–95. https://doi.org/10.31830/2454-1761.2022.012

Yarova, G., Lathrop, W., Nip, J., Bajor, J., Hawkins, S. S., Dasgupta, B. R., Hermanson, K. D., & Mayes, A. (2022). 33261 Topically applied skin natural fatty acids and 12-hydroxystearic acid boosts barrier lipids. Journal of the American Academy of Dermatology, 87(3), AB214. https://doi.org/10.1016/j.jaad.2022.06.888

Yoswathana, N., & Eshiaghi, M. N. (2013). Subcritical water extraction of phenolic compounds from mango seed kernel using response surface methodology. Asian Journal of Chemistry, 25(3), 1741–1744. https://doi.org/10.14233/ajchem.2013.14512a




DOI: http://dx.doi.org/10.62870/jip.v14i1.32306

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