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Bioplastic Based on Taro Starch Modified Polyvinyl Alcohol and Eggshell (Starch-PVA-CT) with Degradability Study
Abstract
Taro (Colocasia esculenta L. Schott) was potentially a raw material in the fabrication of bioplastic because of its biodegradability properties. Egg shells can be used as a filler in bioplastics because of their rich in calcium carbonate (CaCO3). This study aims to examine eggshell addition to starch-PVA-CT bioplastic properties. Taro tuber and eggshell were extracted first to obtain taro starch and calcium carbonate. Obtained products were incorporated with PVA, glycerol, and citric acid to produce bioplastics. Characteristic tests in this study included functional group analysis, hydrophilicity, mechanical properties, and degradation study in rivers. The taro starch obtained from this study was 4.8% from 900 g of taro tubers. Functional group analysis of bioplastics showed the presence of functional groups O-H, C-H, C-O ester, and C=O carbonyl. The hydrophilicity test showed the best percentage of water resistance in CL PVA/starch bioplastic (50% CT), and the decomposition in the river water environment reached 82%. The test results in this study showed that the best variation was in CL PVA/starch bioplastic (25% CT) with a tensile strength value of 2.05 Mpa and elongation at a break of 4%. These results meet the standards of SNI 7188.7:2016.
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Aryanti, N., Kusumastuti, A,Y., & Rahmawati, W. 2017, Pati Talas (Colocasia Esculenta (L) Schott) Sebagai Alternatif Sumber Pati Industri, Jurnal Momentum. Vol. 13, No. 1, hh. 46-52.
Budiman, J., Nopianti, R., & Lestari, D. S. 2018, Karakteristik Bioplastik dari Pati Buah Lindur (Bruguiera Gymnorrizha). Jurnal Teknologi Hasil Perikanan. Vol. 7, No. 1, 49-59.
Cardoso, C.L. E., Parra, F.D., Scagliusi, R. S., Komatsu, H.G.L., & Lugao, B.A. 2021, Effect Of Lonising Radiation Applied to PLA Used As Compatibilizing Agent In Reinforced eGG Shell PBAT/PLA Biobased Composites. Journal of Research Updates in Polymer Science. Vol. 10, hh. 27-33.
Chandrakala, HN.; Ramaraj B.; Shivakumaraiah.; Lee JH. dan Siddaramaiah., 2013, Polyvinyl alcohol/carbon coated zinc oxide nanocomposites: Electrical, optical, structural and morphological characteristics. Journal of Alloys and Compounds. 580:392-400.
Gallo, F., Fossi, C., Weber, R. Santilo, D. Sousa, J., Ingram, I., Nadal, A., & Romano, D. 2019, Marine Litter Plastics and Microplastics and Their Toxic Chemicals Components: The Need for Urgent Preventive Measures. Environmental Science Europe. Vol. 30, No. 13, hh. 1-14.
Hayati, N. dan Lazulva., 2018, Preparing of Cornstarch (Zea Mays)
Bioplastic Using ZnO Metal. Indonesian Journal of Chemical Science and Technology. 1(1):23-30.
Heidarian, P.; Behzad, T. dan Sadeghi, M., 2017, Investigation of Cross-linked PVA/starch Biokomposites Reinforced by Cellulose Nanofibrils Isolated from Aspen Wood Sawdust. Cellulose, 24(8): 3323-3339.
Hilwatullisan., & Hamid, I. 2019, Pengaruh Kitosan dan Plasticizer Gliserol dalam Pembuatan Plastik Biodegradable dari Pati Talas. Prosiding Seminar Nasional II Hasil Litbangyasa Industri, Palembang, 26 Agustus 2019.
Huang, D., Hu Z., Ding, Y., Zhen, Z., Lu, B., Ji, J., & Wang, G. 2019, Seawater Degradable PVA/PCL Blends With Water-Soluble Polyvinyl Alcohol As Degradation Accelerator. Polymer Degradation and Stability. Vol. 163, No. 1, hh. 195-205.
Intandiana, S.; Dawam, H. A.; Denny, R. Y.; Septiyanto, F. R. dan Affifah, I., 2019, Pengaruh Karakteristik Bioplastik Pati Singkong dan Selulosa Mikrokristalin Terhadap Sifat Mekanik dan Hidrofobisitas. EduChemia. Vol. 4, No. 2, hh.185-194.
Kasmuri, N., & Zait, A.S.M. 2018, Enhancement of Bio-plastic using Eggshells and Chitosan on Potato Starch Based. International Journal of Engineering and Technology. Vol. 7, No. 3, hh. 110-115.
Maulida.; Kartika, T,; Harahap, B. M. dan Ginting, S. H. M., 2018, Utilization of mango seed starch in manufacture of bioplastic reinforced with microparticle clay using glycerol as plasticizer, IOP Conference Series: Materials Science and Engineering, 309(1):1–7.
Mulchandani, N.; N. Shah. And T. Mehta., 2017, Synthesis of Chitosan Polyvinyl Alcohol Copolymers for Smart Drug Delivery Application. Polymers and Polymer Composites. 25:241-246.
Napper, I., Thompson, R. 2019, Environmental Deterioration o.f Biodegradable, Oxo-biodegradable, Compostable, and Conventional Plastic Carrier Bags in the Sea, Soil, and Open-Air Over a 3-Year Period. Environmental Science and Technology. Vol. 53, No. 9, hh. 4775-4783.
Novisa, S.; Nugroho, B. B.; Budiastuti, H. dan Manfaati, R., 2020, Characterization and Production of Biodegradable Plastics from Cassava Rubber Starch and Old Newsprint Using Glycerol Plasticizer. Advances in Engineering Research, volume 198.
Nugroho, F.G., Nizardo, NM., & Saepudin, E. 2019, Synthesis of Citric Acid Crosslinked PVA/Tapioca Starch Bioplastic Reinforced with Grafted Cellulose. Proceedings of the 5th International Symposium on Current Progress in Mathematich and Sciences.
Nulik, W.B., 2016, Analisa Pengaruh Suhu Pembentukan Ikatan Crosslink Antara Polyvinyl Alcohol dan Citirc Acid Pada Elektroda Karbon Untuk Proses Desalinasi Larutan NaCl, Institut Teknologi Sepuluh Nopember, Fakultas Matematika dan Ilmu Pengetahuan Alam, Surabaya (Skripsi).
Nuriyah, L., Ganjang, S., & Junaydi, R. 2019, The Effect of Calcium Carbonate Addition to Mechanical Properties of Bioplastic Made from Cassava Starch with Glycerol as Plasticizer. 9th Annual Basic Science International Conference 2019.
Nuriyah, L.; Saroja, G. dan Rohmad, J., 2019, The Effect of Calcium Carbonate Addition to Mechanical Properties of Bioplastic Made from Cassava Starch with Glycerol as Plasticizer. IOP Conf. Series: Materials Science and Engineering 546 (2019).
Ozdamar, E. G.; dan Atez, M., 2018, Rethinking sustainability: A research on starchbased bioplastic., J Sustain. Construct Mater Technol. 3(3): 249-260.
Purnavita, S dan Dewi, C.V. 2021, Kajian Ketahanan Bioplastik Pati Jagung Dengan Variasi Berat dan Suhu Pelarutan Polivinil Alkohol. Journal of Chemical Engineering. Vol. 2, No. 1, hh. 14-22.
Situmorang, U.F., Amna. H. dan Bambang. A.H. 2019, Pengaruh Konsentrasi Pati Ubi Talas (Colocasia esculenta) dan Jenis Plasticizer Terhadap Karakteristik Bioplastik, Jurnal Rekayasa dan Manajemen
Agroindustri. Vol. 7, No. 3, hh. 457-467.
Vanessa. 2019, Pengaruh Ukuran Partikel dan Waktu Pengempa terhadap Sifat Fisik dan Sifat Mekanik Komposit Resin Poliester Berpengisi Serbuk Cangkang Telur ayam (Gallus gallus Domesticus), Universitas Sumatera Utara, Fakultas Teknik, Medan (Skripsi).
Zhong, Y., Godwin, P., Jin, Y. Xiao, H. 2019, Biodegradable Polymers and Green-based Antimicrobial Packaging Materials: A minireview. Advanced Industrial and Engineering Polymer Research. Vol. 2, No. 4, hh. 167-177.
DOI: http://dx.doi.org/10.30870/educhemia.v7i2.14660
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