Engineering of Cassava Stem Cellulose As a Filler for Manufacturing Plastic Biodegradable

Tika Febrianti, Irene Septiriana, Verananda Kusuma Ariyanto, Renaldy Rizky

Abstract


Biodegradable plastic is intensely researched in recently years. Out of many findings, one good finding suggests that lignocellulosic may prove to be one of the most useful alternatives to renewable environmental friendly sources. Cassava stems contain a 56.86 % cellulose. Cellulose from lignocellulosic material has a great impact to strengthen the mechanical properties of biodegradable plastic. Because cellulose has strong and stiff properties, it can be used to produce plastic film. The addition of glycerol helps to reduce the stiff properties of plastic film. This research is purposed to improve the use of cellulose from cassava stems to be a raw material of biodegradable plastic production. There are three methods to produce plastic film: hydrolysis, delignification, and casting of plastic film. IR spectra of biodegradable plastic results a cellulose and chitosan bonding because it has an ester group at wave number 2213 cm-1. SEM analysis of the additional of glycerol cracks the surface of plastic. Degradation analysis shows the use of cellulose increases the degradation rate for bioplastic by losing the mass of sample in three weeks. Tensile strength of bioplastic is not qualified with the specification of conventional polymer but it has good elongation. Therefore, there are necessarily additional materials to increase the tensile strength of bioplastic. 

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References


Damara. 2011. Bahaya Bahan Plastik. Mojokerto: Pusat

Pendidikan Lingkungan Hidup.

Bikiaris, D., J. Prinos, K. Koutsopoulos, N. Vouroutzis, E.

Pavlidou, N. Frangis dan C. Panayiotou. 1997. LDPE/Plasticized Strach Blends Containing PE-g-MA Copolymer as Compatibilizer. J. Polym Degrad and Stab 59:287-291.

http://eprints.polsri.ac.id/1890/3/2.BAB%20II.pdf (diakses

pada tanggal 16 Januari 2017 pada pukul 19.50 WIB).

Sumada, Ketut., Erka Tamara, Puspita., Alqani, Fiqih. Isolation Study of Efficient α - cellulose from Waste Plant Stem Manihot Esculenta Crantz. Jurusan Teknik Kimia, Fakultas Teknologi Industri, UPN “Veteran” Jawa Timur. Jurnal Teknik Kimia Vol. 5, No. 2, April 2011.

Sumartono, Nugroho Wahyu., dkk. 2015. Sintesis dan Karakterisasi Bioplastik Berbasis Alang-alang (Imperata cylindrica (L.)) dengan Penambahan Kitosan, Gliserol dan Asam oleat. FMIPA, UNY.

S.L. Ezeoha dan J.N. Ezenwanne. “Production of Biodegradable Plastic Packaging Film From Cassava Starch”. IOSR Journal of Engineering (IOSRJEN). Vol. 3 Issue 10. October 2013.

Cerqueira, M. A., Souza, B. W. S., Teixeira, J.A., Vicente, A. A., 2011. Effect of Glycerol and corn oil on physicochemical properties of polysaccharide films – Acomparative study. Food Hydrocolloids 27 (2012) 175-184.

Suendo, V., Ahmad, L. O., & Valiyaveetiil, S. 2010. Deasetilisasi Kitin secara bertahap dan pengaruhnya terhadap derajat deasetilisasi serta massa molekul kitosan. Journal Kimia Indonesia, 5(1), 17-21.

World Chemical Engineering Journal Vol.1, No.5, (2017), pp. 58 – 64

Isroi, Wibowo, Nendyo Adhi., Millati, Ria., Syamsiyah, Siti., Bachrudin, Zaenal. 2013. Effect of Manganase and Copper on Biological Pretreatment of Oil Palm Empty Fruit Bunches.

Florencia., Versino., Lopez, Olivia V., Garcia, M. Alejandra. 2015. Sustainable use of Cassava (Manihot esculenta) Roots as Raw Material Biocomposites Development. Elsevier: Journals of Industrial Crops and Products Vol. 65: 78-89.

Liu, H., Adhikara, R., Guo, Q., & Adhikara, B. 2013. Preparation and characterization of glycerol plasticized (high-amylose)starch-chitosan films. Journal of Food Engineering 116 (2013) 588-597.

Coniwati, Pamilia., Laila, Linda., Alfira, Mardiyah Rizka. 2014. Pembuatan Film Plastik Biodegradabel dari Pati Jagung dengan Penambahan Kitosan dan Pemlastis Gliserol. Jurnal Teknik Kimia Universitas Brawijaya No. 4, Vol. 20: 22-30.

Wardhani, Riesca Ayu Kusuma., Rudyardjo, Djony Izak., Supardi, Ardi. 2012. Sintesis dan Karakterisasi Bioselulosa-Kitosan dengan Penambahan Gliserol sebagai Plasticizer. Fakultas Sains dan Teknologi: Universitas Airlangga.




DOI: http://dx.doi.org/10.62870/wcej.v1i5.1995

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