Synergistic Ability of Tannin – Silica as a Corrosion Inhibitor with the Addition of KI to Mild Steel in Demineralized Water

Hendra Arief, Marta Pramudita, Alia Badra Pitaloka

Abstract


The rapid industrial growth in Indonesia today requires effective and efficient operating and maintenance conditions. The application of corrosion protection in cooling towers and boilers shows that inhibitor materials such as nitrates, nitrites and chromates must be used in large concentrations; these inhibitors also cause environmental pollution. For this reason, bio-inhibitors derived from natural ingredients have begun to be developed. Tannins and silica are widely known as effective inhibitors in controlling carbon steel corrosion. The synergistic mechanism of inhibitors is known to increase the effectiveness of inhibitory substances. This study aims to study the effectiveness and understand the mechanism of tannin and silica inhibitors and the effect of adding potassium iodide. as a synergistic inhibitor. This study used samples of mild steel carbon steel with demineralized water media at a temperature variation of 30-60oC and immersion time of 1, 2 and 3 hours. Variations in the concentration of tannins and silica used are 0-1250 ppm, and the corrosion measurement method uses the weight loss method. The results showed that adding potassium iodide. They have increased the ability of mild steel corrosion inhibitors produced by tannin-silica synergy. The corrosion rate of mild steel can be reduced by 82.95% at a concentration of tannin-silica-KI 1250 ppm. Therefore, tannin-silica synergy with the addition of potassium iodide. It has the potential to be a good alternative in the use of corrosion inhibitors for mild steel in demineralized water.

Full Text:

PDF

References


Alaneme, K. K., Daramola, Y. S., Olusegun, S. J., & Afolabi, A. S. (2015). Corrosion inhibition and adsorption characteristics of rice husk extracts on mild steel immersed in 1M H2SO4 and HCl solutions. International Journal of Electrochemical Science, 10(4), 3553–3567.

Alaneme, K. K., Olusegun, S. J., & Adelowo, O. T. (2016). Corrosion inhibition and adsorption mechanism studies of seed husk extracts on mild steel immersed in acidic solutions. Alexandria Engineering Journal, 55(1), 673–681. https://doi.org/10.1016/j.aej.2015.10.009

Aramco, S. (2019). The Saudi Aramco Journal of Technology. Saudi Aramco.

Asdim. (2008). Penghambatan Reaksi Korosi Baja Dengan Menggunakan Ekstrak Kulit Buah Manggis (Garcinia Mangostana L) Sebagai Inhibitor Dalam Larutan Garam. Jurnal Gradien, 4(1), 304–307.

Astm. (2012). ASTM Standards: G31-72. In Annual Book of ASTM Standards. https://doi.org/10.1520/G0031-72R04

Ávila-Gonzalez, C., Cruz-Silva, R., Menchaca, C., Sepulveda-Guzman, S., & Uruchurtu, J. (2011). Use of silica tubes as nanocontainers for corrosion inhibitor storage. Journal of Nanotechnology, 2011. https://doi.org/10.1155/2011/461313

Awizar, D. A., Othman, N. K., Jalar, A., Daud, A. R., Rahman, I. A., & Al-Hardan, N. H. (2013). Nanosilicate extraction from rice husk ash as green corrosion inhibitor. International Journal of Electrochemical Science, 8(2), 1759–1769.

Awizar, D. A., Othman, N. K., Jalar, A., & Rahman, I. A. (2013). Nanosilicate Extraction from Rice Husk Ash as Green Corrosion Inhibitor. May 2014.

Azha, S. F., Shamsudin, M. S., Shahadat, M., & Ismail, S. (2018). Low cost zwitterionic adsorbent coating for treatment of anionic and cationic dyes. Journal of Industrial and Engineering Chemistry, 67. https://doi.org/10.1016/j.jiec.2018.06.029

Behpour, M., Ghoreishi, S. M., Khayatkashani, M., & Soltani, N. (2012). Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract of Punica granatum peel and main constituents. Materials Chemistry and Physics, 131(3), 621–633. https://doi.org/10.1016/j.matchemphys.2011.10.027

Benali, O., Benmehdi, H., Hasnaoui, O., Selles, C., & Salghi, R. (2013). Green corrosion inhibitor: Inhibitive action of tannin extract of Chamaerops humilis plant for the corrosion of mild steel in 0.5M H2SO4. Journal of Materials and Environmental Science, 4(1), 127–138.

Darmawan, O. (2012). Studi Green Corrosion Inhibitor Ekstrak Daun bayam Merah (Amaranthus Gangeticus) pada Baja Karbon Rendah dalam Larutan 1 M HCl dengan Metode Polarisasi dan EIS. 1–86.

Deny, S. (2019). Industri di RI Berkembang Pesat dalam 10 Tahun Terakhir.

Fachry, A. R., Sastrawan, R. A., & Guntur, S. (2012). Kondisi Optimal Proses Ekstraksi Tanin dari Daun Jambu Biji Menggunakan Pelarut Etanol.

Farochi, M. B. F. (2014). Pengaruh Penambahan Ekstrak Daun Salam (Eugenia polyantha) terhadap Laju Korosi pada Baja Karbon API 5L Grade B di Lingkungan NaCl 3,5% dan H2SO4 1M.

Fontana. (2013). Ebooks Chemical Engineering Corrosion Engineering.

Fontana, M. G. (1947). Corrosion. Industrial and Engineering Chemistry, 39(12), 91 A-92 A. https://doi.org/10.1021/ie50456a786

Fu, W., Song, X., Tian, R., Lei, Y., Long, W., Zhong, S., & Feng, J. (2020). Wettability and joining of SiC by Sn-Ti: Microstructure and mechanical properties. Journal of Materials Science and Technology, 40. https://doi.org/10.1016/j.jmst.2019.08.040

Gusti, D. R., Farid, F., & Lestari, I. (2013). Ekstrak Kulit Kayu Akasia Sebagai Inhibitor pada Laju Korosi Baja Lunak dalam Media Asam Sulfat. Prosiding Semirata FMIPA Universitas Lampung, 99–102.

Hagerman, A. E. (2002). Tannin Handbook. Condensed Tannin Structural Chemistry, Hlm 85-88.

Hao, Y., Sani, L. A., Ge, T., & Fang, Q. (2017). The synergistic inhibition behaviour of tannic acid and iodide ions on mild steel in H2SO4 solutions. Corrosion Science, 123, 158–169. https://doi.org/10.1016/j.corsci.2017.05.001

Harvey, I. M., & Baker, R. M. (2002). Chemical Analysis in the Laboratory: A Basic Guide. Royal Society Chemistry.

Hassan, K. H., Khadom, A. A., & Kurshed, N. H. (2016). Citrus aurantium leaves extracts as a sustainable corrosion inhibitor of mild steel in sulfuric acid. South African Journal of Chemical Engineering, 22, 1–5. https://doi.org/10.1016/j.sajce.2016.07.002

Heidersbach, R. (2010). Metallurgy and Corrosion Control in Oil and Gas Production. In Metallurgy and Corrosion Control in Oil and Gas Production. https://doi.org/10.1002/9780470925782

Indrayani, N. L. (2016). Studi Pengaruh Ekstrak Eceng Gondok Sebagai Inhibitor Korosi Untuk Pipa Baja Ss400 Pada Lingkungan Air. 4(2), 47–56.

Jalaluddin, Ishak, R. (2014). Efektifitas Inhibitor Ekstrak Tanin Kulit Kayu Akasia (Acacia Mangium) Terhadap Laju Korosi Baja Lunak (St.37) Dalam Media Asam Klorida. Angewandte Chemie - International Edition, 53(1), 151–155. https://doi.org/10.1002/anie.201308264

Kang, W., Zhu, Z., Yang, H., Tian, S., Wang, P., Zhang, X., & Lashari, Z. A. (2019). Study on the association behavior of a hydrophobically modified polyacrylamide in aqueous solution based on host-guest inclusion. Journal of Molecular Liquids, 275. https://doi.org/10.1016/j.molliq.2018.11.063

Kembaren, L. (2020). RI Naik Kelas Jadi Negara Maju ini Kata Sri Mulyani.

Li, X., Deng, S., Fu, H., & Xie, X. (2014). Synergistic inhibition effects of bamboo leaf extract/major components and iodide ion on the corrosion of steel in H3PO4 solution. Corrosion Science, 78, 29–42. https://doi.org/10.1016/j.corsci.2013.08.025

Liao, L. L., Mo, S., Luo, H. Q., & Li, N. B. (2017). Longan seed and peel as environmentally friendly corrosion inhibitor for mild steel in acid solution: Experimental and theoretical studies. Journal of Colloid and Interface Science, 499, 110–119. https://doi.org/10.1016/j.jcis.2017.03.091

Ludiana, Y., & Handani, S. (2012). Pengaruh Konsentrasi Inhibitor Ekstrak Daun Teh ( C Amelia Sinensis ) Terhadap Laju Korosi Baja Karbon Schedule 40 Grade B Erw. Jurnal Fisika Unand, 1(1), 12–18.

Lysogorski, D., Hartt, W., & Ananthakrishnan, P. (2003). Technical note: A modified potential attenuation equation for cathodically polarized marine pipelines and risers. Corrosion, 59(8). https://doi.org/10.5006/1.3277597

Mehdi Yari. (2017). The 6 Corrosive Components That Can Be Found in Crude Oil. Corrosionpedia.

Mohammadi, Z., & Rahsepar, M. (2019). The use of green Bistorta Officinalis extract for effective inhibition of corrosion and scale formation problems in cooling water system. Journal of Alloys and Compounds, 770, 669–678. https://doi.org/10.1016/j.jallcom.2018.08.198

Movahedi-Rad, A., & Alizadeh, R. (2017). Dependence of Strain Rate Sensitivity on the Slip System: A Molecular Dynamics Simulation. Journal of Materials Engineering and Performance, 26(11). https://doi.org/10.1007/s11665-017-2977-z

Mulyaningsih, N., Mujiarto, S., & Gyani. (2019). Pengaruh Daun Jambu Biji sebagai Inhibitor Korosi Alami Rantai Kapal. Journal of Mechanical Engineering, 3(1).

Nathan, C. C. (1973). Corrosion Inhibitors. In NACE Publication. National Association of Corrosion Engineers.

Noor R, T., Kusuma W, S., Purniawan, A., Agung K, B., & Sulistijono. (2015). Pengaruh Penambahan Ekstrak Kulit Buah Jeruk dan Kulit Buah Mangga sebagai Inhibitor Korosi pada Baja Karbon dalam Media NaCl 3,5%. 29–33.

Noor, T., Kusuma, S., Purniawan, A., Agung, B., & Sulistijono. (2015). Pengaruh Penambahan Ekstrak Kulit Buah Jeruk dan Kulit Buah Mangga sebagai Inhibitor Korosi pada Baja Karbon dalam Media NaCl 3,5%. 29–33.

Obot, I. B., Obi-Egbedi, N. O., Umoren, S. A., & Ebenso, E. E. (2010). Synergistic and antagonistic effects of anions and ipomoea invulcrata as green corrosion inhibitor for aluminium dissolution in acidic medium. International Journal of Electrochemical Science, 5(7), 994–1007.

Oguzie, E. E. (2008). Evaluation of the inhibitive effect of some plant extracts on the acid corrosion of mild steel. Corrosion Science, 50(11), 2993–2998. https://doi.org/10.1016/j.corsci.2008.08.004

Ohtsuka, T., Nishikata, A., Sakairi, M., & Fushimi, K. (2018). Electrochemistry for Corrosion Fundamentals. Springer.

Okyere, M. S. (2019). Corrosion Protection for the Oil and Gas Industry. In Corrosion Protection for the Oil and Gas Industry. https://doi.org/10.1201/9780429056451

Pradityana, A., Sulistijono, & Shahab, A. (2014). Penggunaan bio inhibitor dalam pipe plant industri migas.

Pramudita, M., Sukirno, & Nasikin, M. (2018a). Influence of tannin content in Terminalia catappa leaves extracts resulted from maceration extraction on decreasing corrosion rate for mild steel in 1M H2SO4. IOP Conference Series: Materials Science and Engineering, 345(1). https://doi.org/10.1088/1757-899X/345/1/012023

Pramudita, M., Sukirno, & Nasikin, M. (2020). Performance of Terminalia Catappa Leaves Extract as Bio-Corrosion Inhibitor for Mild Steel in H2SO4 Solution. IOP Conference Series: Materials Science and Engineering, 796(1). https://doi.org/10.1088/1757-899X/796/1/012059

Pramudita, M., Sukirno, S., & Nasikin, M. (2018b). Rice Husk Extracts Ability to Reduce the Corrosion Rate of Mild Steel. International Journal of Chemical Engineering and Applications, 9(4), 143–146. https://doi.org/10.18178/ijcea.2018.9.4.715

Pramudita, M., Sukirno, S., & Nasikin, M. (2019). Synergistic Corrosion Inhibition Effect of Rice Husk Extract and KI for Mild Steel in H2SO4 Solution. BCREC.

Prayogi, R. (2017). Aplikasi Kulit Mangga (Mangifera Indica L) sebagai Inhibitor Organik Korosi pada Baja API 5L Grade B dalam Media 1M HCL. Departemen Teknik Mesin Industri, ITS, 2(1), 1–128.

Putra, R. A. (2011). Pengaruh Waktu Perendaman Dengan Penambahan Ekstrak Ubi Ungu Sebagai Inhibitor Organik Pada Baja Karbon Rendah Di Lingkungan Hcl 1m.

Qiu, L. G., Wu, Y., Wang, Y. M., & Jiang, X. (2008). Synergistic effect between cationic gemini surfactant and chloride ion for the corrosion inhibition of steel in sulphuric acid. Corrosion Science, 50(2), 576–582. https://doi.org/10.1016/j.corsci.2007.07.010

Rajendran, S., & Singh, G. (2020). Titanic Corrosion. In Taylor & Francis. Jenny Stanford Publishing. https://doi.org/10.1017/CBO9781107415324.004

Roberge, P. R. (2000). Handbook of Corrosion inhibitors. In Metal Finishing (Vol. 98, Issue 10). https://linkinghub.elsevier.com/retrieve/pii/S0026057600834455

Rochmat, A., Liantony, G., & Septiananda, Y. D. (2019a). Uji Kemampuan Tanin Daun Ketapang Sebagai Inhibisi Korosi Pada Baja Mild Steel Dalam Pipeline. Jurnal Integrasi Proses, 8(1), 45. https://doi.org/10.36055/jip.v8i1.5601

Rochmat, A., Liantony, G., & Septiananda, Y. D. (2019b). Uji Kemampuan Tanin Daun Ketapang sebagai Inhibisi Korosi pada Baja Wild Steel dalam Pipeline. Jurnal Integrasi Proses, 8(1), 45–50.

Rufaida, H. A. (2016). Studi Efektifitas Ekstrak Daun Asam Jawa Dan Ekstrak Kulit Melinjo Sebagai Inhibitor Organik Pada Baja Api 5l Grade B Di Lingkungan Nacl 3,5 % Ph 5.

Salasi, M., Shahrabi, T., Roayaei, E., & Aliofkhazraei, M. (2007). The electrochemical behaviour of environment-friendly inhibitors of silicate and phosphonate in corrosion control of carbon steel in soft water media. 104, 183–190. https://doi.org/10.1016/j.matchemphys.2007.03.008

Shen, Y. (2017). Rice husk silica derived nanomaterials for sustainable applications. Renewable and Sustainable Energy Reviews, 80(November 2016), 453–466. https://doi.org/10.1016/j.rser.2017.05.115

Shoog, D. A., & West, D. M. (1976). Fundamentals of analytical chemistry. https://doi.org/10.1016/b978-0-323-85208-1.00006-1

Society, A. W. (2000). Guide for Welding Mild Steel Pipe.

Swain, & Schultz. (1997). Corrosion basics. 1996.

Tambun, R., Limbong, H. P., Nababan, P., & Sitorus, N. (2015). Kemampuan Daun Jambu Biji sebagai Inhibitor Korosi Besi pada Medium Asam Klorida. In Jurnal Kimia dan Kemasan (Vol. 37, Issue 2, p. 73). https://doi.org/10.24817/jkk.v37i2.1815

Tan, K. W., & Kassim, M. J. (2011). A correlation study on the phenolic profiles and corrosion inhibition properties of mangrove tannins ( Rhizophora apiculata ) as affected by extraction solvents. Corrosion Science, 53(2), 569–574. https://doi.org/10.1016/j.corsci.2010.09.065

Thirumangalam Karunanithi, B., & Chellappa, J. (2019). Adsorption and inhibition properties of Tephrosia Purpurea as corrosion inhibitor for mild steel in sulphuric acid solution. Journal of Dispersion Science and Technology, 40(10), 1441–1450. https://doi.org/10.1080/01932691.2018.1516150

Turnip, L. B., Handayani, S., & Mulyadi, S. (2015). Pengaruh Penambahan Inhibitor Ekstrak Kulit Buah Manggis terhadap Penurunan Laju Korosi Baja ST-37. Jurnal Fisika Unand, 4(2), 144–149.

Umoren, S. A., Ogbobe, O., Okafor, P. C., & Ebenso, E. E. (2007). Polyethylene glycol and polyvinyl alcohol as corrosion inhibitors for aluminium in acidic medium. Journal of Applied Polymer Science, 105(6), 3363–3370. https://doi.org/https://doi.org/10.1002/app.26530

Umoren, S. A., & Solomon, M. M. (2015). Effect of halide ions on the corrosion inhibition efficiency of different organic species - A review. Journal of Industrial and Engineering Chemistry, 21, 81–100. https://doi.org/10.1016/j.jiec.2014.09.033

Utomo, B. (2019). Jenis Korosi Dan Penanggulangannya. Kapal, 6(2), 138–141.

Valcárcel Cases, M., López-Lorente, Á. I., & López-Jiménez, M. Á. (2018). Foundations of Analytical Chemistry. In Foundations of Analytical Chemistry. https://doi.org/10.1007/978-3-319-62872-1

Wahyuni, T., & Syamsudin, A. (2014). Pemanfaatan Tanin Ekstrak Daun Jambu Biji terhadap Laju Korosi Besi dalam Larutan NaCl 3% (w/v). Jurnal Konversi, 3(1), 45–52.

Williams, J. C. (2006). Engineering Materials and Processes.

Yanuar, A. P., Pratikno, H., & Titah, H. S. (2017). Pengaruh Penambahan Inhibitor Alami terhadap Laju Korosi pada Material Pipa dalam Larutan Air Laut Buatan. Jurnal Teknik ITS, 5(2), 8–13. https://doi.org/10.12962/j23373539.v5i2.18938

Yesu Thangam, Y., Kalanithi, M., Anbarasi, C. M., & Rajendran, S. (2009). Inhibition of corrosion of carbon steel in a dam water by sodium molybdate - Zn2+ system. Arabian Journal for Science and Engineering, 34(2 C), 49–60.




DOI: http://dx.doi.org/10.36055/wcej.v7i1.20626

Refbacks

  • There are currently no refbacks.


Copyright (c) 2023 World Chemical Engineering Journal

WCEJ (e-ISSN: 2443-2261) is published by Chemical Engineering Department, Universitas Sultan Ageng Tirtayasa (UNTIRTA).

This Journal has been indexed by:

  1. Google Scholar
  2. Garuda
  3. Dimensions
  4. Crossref
  5. Open Academic Journal Index
  6. Journal Impact Factor
  7. Cite Factor 
Archives: Resources | Dimensions CrossrefJIFACTOR, Journal Indexing  

 

 

Creative Commons License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.