Reverse Flow Reactor for Catalytic Oxidation of Lean Methane

Teguh Kurniawan, Yogi Wibisono Budhi, Yazid Bindar

Abstract


Methane as a potential green house gases contributor which gives 21 GWP has to be mitigated to diminish the global warming effect. High concentration methane can be easily converted into CO2 by mean oxidation. However lean methane can only be oxidized in catalytic reaction system as the catalyst lowers the reaction temperature up to 400 oC. Nevertheless, this is still high temperature to achieve by low concentration and low temperature feed. It still needs preheating the feed until its reaction condition reached which can be supplied outside or within the system called auto thermal. One of promising auto thermal reactor is reverse flow reactor which is the reactor that its feed flow periodically switches to make the heat trapped inside the reactor. In this work we have designed reverse flow reactor by one-dimensional model, pseudohomogeneous for mass and heterogeneous for energy to burn lean methane from a station compressor. The critical parameter of switching time on the system of periodical reversal is also presented

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References


Balaji, S.; Lakshminarayanan, S. 2005. Heat removal from reverse flow reactors used in methane combustion. The Canadian Journal of Chemical Engineering. 83.

Baressi, A. A.; Baldi, G; Fissore, D. 2007, Forced Unsteady-State Reactors as Efficient Devices for Integrated Processes: Case Histories and New Perspectives. Industrial & Engineering Chemistry Research. 46 (25).

Bosomiu, M.; Bozga, G.; Soare, G. 2008. Methane Combustion Over a Commercial Platinum on Alumina Catalyst: Kinetics and Catalyst

Deactivation. Revue Roumaine de Chimie., 53(12), 1105–1115.

Effendy, M.; Budhi, Y. W.; Bindar, Y.; Subagjo. 2009. Penentuan metode operasi reverse flow reactor dengan umpan fluktuatif dalam pengolahan emisi gas metana di stasiun kompresor, Prosiding SNTKI, Bandung, Indonesia, 19-20 Oktober.

Eigenberger, G.; Nieken, U. 1988. Catalytic Combustion with Periodic Flow Reversal. Chemical Engineering Science., 43, 2109–2115.

Gawdzik, A.; Rakowski, L. 1989. The methods of analysis of the dynamic properties of the adiabatic tubular reactor with switch flow. Computers Chemical Engineering., 13 (10), 1165-1173.

Hayes, R. E.; Kolaczkowski, S. T.; 1997. Introduction to catalytic combustion, Gordon and Breach, Amsterdam.

Hayes, R. E.; Kolaczkowski, S. T.; Li, P. K.; Awdry, S. 2001. The palladium catalyzed oxidation of methane: reaction kinetics and the effect of diffusion barriers. Chemical Engineering Science., 56, 4815-4835.

Hayes, R. E. 2004. Catalytic solutions for fugitive methane emissions in the oil and gas sector. Chemical Engineering Science., 59, 4073-4080.

Kushwaha, A.; Poirier, M.; Sapoundjiev, H.; Hayes, R. E. 2004. Effect of reactor internal properties on the performance of a flow reversal catalytic reactor for methane combustion. Chemical Engineering

Science., 59, 4081–4093.

Kolios G.; Frauhammer, J.; Eigenberger, G. 2000. Review autothermal fixed-bed reactor concepts. Chemical Engineering Science., 55, 5945-5967.

Lee, J. H.; Trimm, D. L. 1995. Catalytic combustion of methane. Fuel Processing Technology, 42, 339-359.

Litto, R.; Hayes, R. E.; Liu, B. 2006. Capturing fugitive methane emissions from natural gas compressor buildings, Journal of Environmental Management., 84 (3), 347-361.

Matros, Y. S; Bunimovich, G. A. 1996. Reverse flow operation in fixed bed catalytic reactors. Catal. Rev.-sci. eng., 38 (1), 1-68.

Moore, S.; Freund, P.; Riemer, P.; Smith, A.; 1998. Abatement of methane emissions, IEQ Greenhouse Gas R&D Programme, Cheltenham.

Otto, K. 1989. Methane Oxidation over Pt on γAlumina: Kinetics and Structure Sensitivity. Langmuir., 5, 1364-1369.

Annonymous. FlexPDE 6, PDE Solutions Inc, 2006.

Salomons, S.; Hayes, R. E.; Poirier, M.; Sapoundjiev, H. 2003. Flow reversal reactor for catalytic combustion of lean methane mixtures. Catalysis Today., 83, 59–69.

Sapoundjiev, H.; Aube, F.; 1999. Catalytic flow reversal reactor technology: an opportunity for heat recovery and greenhouse gas elimination from mine ventilation air, Canmet energy technology

centre, Varennes, Canada.

Schäfer, M. 2006. Computational Engineering – Introduction to Numerical Methods, Springer, Berlin; p. 107.




DOI: http://dx.doi.org/10.62870/wcej.v2i1.3493

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