Effect of magnetic field on the behavior of Electrochemical oxidation of Aluminum in 3.5% NaCl solution

Surya Darma, Sukarno Sukarno, Bambang Soegijono, Hamdan Akbar Notonegoro, Naila Mubarok

Abstract


An irreversible electrochemical reaction from material interaction with the environment and causing degradation is known as corrosion. The electrolyte changes significantly affect the corrosion's reaction kinetics. Unknown factors and various notable factors influence the corrosion rate of a particular material in the environmental system. Significant interest in magnetic fields and their effects on electrochemical reactions have recently been gained. This paper studies the effect of an external magnetic field on the electrochemical oxidation of Aluminum (Al) in a 3,5% NaCl solution. The magnetic field 0; 0,8; 1,4; and 2,1 Tesla were used to expose the samples during corrosion testing. We found that the effect of a magnetic field on electrochemical oxidation shifts the oxidation potential to higher or lower than the oxidation potential without a magnetic field. Moreover, the oxidation potential's value depends on the magnetic field's intensity.

Keywords


magnetic effect, corrosion, electrochemical, aluminum

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References


Jones DA. Principles and Prevention of Corrosion. 2nd ed.

Singapore: Macmillan Publishing Company; 1992.

Aaboubi O, Chopart JP, Douglade J, Olivier A. Magnetic Field

Effects on Mass Transport. J Electrochem Soc.

;137(6):1796–804.

Tacken RA, Janssen LJJ. Applications of

magnetoelectrolysis. J Appl Electrochem. 1995;25:1–5.

Aogaki R, Fueki K, Mukaibo T. Application of

Magnetohydrodynamic Effect to the Analysis of

Electroehemical Reactions－1．MHD Flow of an

Electrolyte Solution in an Electrode－Cell with a short

Rectangular Channel. Denki Kagaku oyobi Kogyo

Butsuri Kagaku. 1975;43(9):504–8.

Rucinskiene A, Bikulcius G, Gudaviciute L, Juzeliunas E.

Magnetic field effect on stainless steel corrosion in

FeCl3 solution. Electrochem commun. 2002 Jan

;4:86–91.

Chiba A, Tanaka N, Ueno S, Ogawa T. Inhibition by Magnetic

Fields of the Corrosion of Iron in Sodium Chloride

Solution. Zairyo-to-Kankyo. 1992;41(5):287–92.

Zhang X, Wang Z, Zhou Z, Yang G, Cai X. Intermetallics

Impact of magnetic field on corrosion performance of

Al – Mg alloy with different electrode potential phases.

Intermetallics [Internet]. 2021;129:107037. Available

from:

https://doi.org/10.1016/j.intermet.2020.107037

Chopart JP, Douglade J, Fricoteaux P, Olivier A.

Electrodeposition And Electrodissolution Of Copper

With A Magnetic Field : Dynamic And Stationary

Investigations. Electrochim Acta. 1991;36(3-4):459–

Chia-Chien L, Chou T-C. Effects of magnetic field on the

reaction kinetics of electroless nickel deposition.

Electrochim Acta [Internet]. 1995;40(8):965–70.

Available from:

https://www.sciencedirect.com/science/article/pii/0

Shinohara K, Aogaki R. Magnetic Field Effect on Copper

Corrosion in Nitric Acid. Electrochemistry.

;67:126–31.

Hinds G, Coey JMD, Lyons MEG. Magnetoelectrolysis of

copper. 1998;6447:81–4.

Costa I, Oliveira M, De MHG, Faria RN. An Investigation on

the Corrosion Behaviour of Nd-Fe-B Magnets in a

Chloride Solution. Mater Sci Forum. 2005;498-499:98–

Hayashi H, Nonaka C, Tozaki K, Inabaa H, Uyeda C. Effect of

the magnetic field on the ferroelectric transition of KD

PO 4 measured by a high resolution and supersensitive differential scanning calorimeter.

Thermochim Acta. 2005;431:200–4.

Grant K, Hemmert J, White H. Magnetic focusing of redox

molecules at ferromagnetic microelectrodes.

Electrochem Commun - Electrochem COMMUN.

;1:319–23.

Zhang H, Li X, Pang J, Yin L, Ma H, Li Y, et al. Non-monotonic

influence of a magnetic field on the electrochemical

behavior of Fe78Si9B13 glassy alloy in NaOH and NaCl

solutions. Int J Miner Metall Mater. 2014;21(10):1009–

Yang Y, Luo Y, Sun M, Wang J. Effect of Magnetic Field on

Corrosion Behavior of X52 Pipeline Steel in Simulated

Soil Solution. Int J Electrochem Sci. 2021;16:211010.

Dearnley PA, Mallia B. The chemical wear ( corrosion-wear

) of novel Cr based hard coated 316L austenitic

stainless steels in aqueous saline solution. Wear

[Internet]. 2013;306(1-2):263–75. Available from:

http://dx.doi.org/10.1016/j.wear.2012.09.002

Brondel D, Edwards R, Hayman A, Hill D, Semerad T.

Corrosion in the Oil Industry. :4–69.

Pondichery S. A Study On The Effects Of A Magnetic Field

On The Corrosion Behavior Of Materials. The

University Of Texas At Arlington; 2014.

Okonkwo PC, Adel MMA. Erosion-Corrosion In Oil And Gas

Industry : A Review. Int J Metall Mater Sci Eng.

;4(3):7–28.

Fan ZD, Du JS, Zhang ZB, Ma YC, Cao SY, Niu K, et al. Internal

leakage of plate heat exchangers caused by

cooperation of pitting, crevice corrosion, and fretting.

Eng Fail Anal [Internet]. 2019;96:340–7. Available

from:

https://doi.org/10.1016/j.engfailanal.2018.10.007




DOI: http://dx.doi.org/10.36055/fwl.v0i0.14703

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